Great answer from Brian, good to have this structural info/reminder.
I have over 120 gal of storage in two belly tanks, and I could have squeezed a bit more in there with some more careful design.
I'm a big proponent of having dual belly tanks, as this allows me to play around with trim a lot more. So far I always benefit with less weight aft, so I always burn from my aft fuel tank first, improving trim as my trip progresses.
In addition to improving your ability to control trim, I like the simple redundancy this provides. Of course, two tanks is a more expensive option and you lose a little bit of volume because you cannot simply butt the tanks right up next to each other - mine are aluminum, and it needs some space to breathe.
Finally, since you have plenty time, take a close look through all the shapes Moeller offers in rota-molded tanks. These are superior to aluminum in that there are no corrosion issues and they are lighter.